How can I print an A5 page on A4 paper without it being scaled?

DVIview automatically scales your document pages to fit on the paper size you're actually using in your printer. If you don't want scaling then select the same paper size for your document as is selected for the printer and use the page offset dialogue to position your pages on that paper. When you print, DVIview will see that the pages and the printer paper are the same size and so won't scale.